Tlhahlobo le Litlhahiso tsa ho Sireletsa Mollo bakeng sa Liaparo tsa ho Arohanya Libetri

Tlhahlobo le Litlhahiso tsa ho Sireletsa Mollo bakeng sa Liaparo tsa ho Arohanya Libetri

Moreki o hlahisa di-separator tsa betri, mme bokaholimo ba se-separator bo ka manehoa ka lera, hangata alumina (Al₂O₃) ka sekotwana se senyenyane sa binder. Jwale ba batla di-retant tse ding tsa malakabe ho nkela alumina sebaka, ka ditlhoko tse latelang:

• Ho thibela malakabe ka katleho ho 140°C(mohlala, ho bola ho lokolla dikhase tse sa sebetseng).
• Botsitso ba motlakasele ho tsamaellana le likarolo tsa betri.

Litšireletso tsa Mollo tse Khothaletsoang le Tlhahlobo

1. Dintho tse thibelang malakabe a tshwanang le a Phosphorus-Nitrogen (mohlala, Modified Ammonium Polyphosphate (APP) + Melamine)

Mokhoa:

• Mohloli oa asiti (APP) le mohloli oa khase (melamine) lia sebelisana ho lokolla NH₃ le N₂, li qhibilihisa oksijene le ho etsa lera la char ho thibela malakabe.
  Melemo:
• Ho sebelisana ha phosphorus le naetrojene ho ka fokotsa mocheso oa ho bola (o ka fetoloang ho ~140°C ka nano-size kapa formula).
• N₂ ke khase e sa sebetseng; Tšusumetso ea NH₃ ho electrolyte (LiPF₆) e hloka tlhahlobo.
  Lintho tse lokelang ho nahanoa:
• Netefatsa botsitso ba APP ho di-electrolyte (qoba ho hydrolysis ho ba phosphoric acid le NH₃). Ho kwahela ka silika ho ka ntlafatsa botsitso.
• Teko ea ho lumellana ha electrochemical (mohlala, cyclic voltammetry) ea hlokahala.

2. Lintho tse thibelang malakabe tse thehiloeng ho naetrojene (mohlala, Sistimi ea Azo Compound)

Mokhethoa:Azodicarbonamide (ADCA) e nang le di-activator (mohlala, ZnO).
Mokhoa:

• Mocheso oa ho bola o ka fetoloang ho 140–150°C, o lokolla N₂ le CO₂.
  Melemo:
• N₂ ke khase e sa sebetseng hantle, e se nang kotsi ho libeteri.
  Lintho tse lokelang ho nahanoa:
• Lihlahisoa tse ling tsa taolo (mohlala, CO, NH₃).
• Microencapsulation e ka ntlafatsa mocheso oa ho bola hantle.

3. Mekhoa ea Karabelo ea Khabone/Asiti (mohlala, NaHCO₃ e kentsoeng ka har'a microcapsulated + Mohloli oa Asiti)

Mokhoa:

• Li-microcapsule lia phatloha ka mocheso oa 140°C, e leng se bakang karabelo pakeng tsa NaHCO₃ le asiti ea organic (mohlala, citric acid) ho lokolla CO₂.
  Melemo:
• CO₂ ha e sebetse hantle ebile e bolokehile; mocheso oa karabelo o ka laoleha.
  Lintho tse lokelang ho nahanoa:
• Li-ion tsa sodium li ka sitisa ho tsamaisoa ha Li⁺; nahana ka letsoai la lithium (mohlala, LiHCO₃) kapa ho sitisa Na⁺ ho sisinyeha ha lesela.
• Ntlafatsa ho kenngoa ha capsule bakeng sa botsitso ba mocheso oa kamore.

Mekhoa e meng e ka khonehang

• Meralo ea Tšepe le ea Organic (MOFs):mohlala, ZIF-8 e a bola mochesong o phahameng ho ntsha kgase; e sireletsa di-MOF tse nang le mocheso o tshwanang wa ho bola.
• Phosphate ea Zirconium (ZrP):E etsa lera la thibelo ha mocheso o senyeha, empa e ka hloka boholo bo boholo ho fokotsa mocheso oa ho senyeha.

Litlhahiso tsa Liteko

1. Tlhahlobo ea Thermogravimetric (TGA):Fumana mocheso oa ho bola le thepa ea ho ntša khase.
2. Teko ea Elektrok'hemik'hale:Lekola tšusumetso ho conductivity ea ionic, interfacial impedance, le ts'ebetso ea ho palama baesekele.
3. Teko ea ho Fokotsa Lelakabe:mohlala, teko ea ho chesa ka ho otloloha, tekanyo ea ho fokotseha ha mocheso (ho 140°C).

Qetello

Thesethibela-mollo sa phosphorus-naetrojene se fetotsweng (mohlala, APP e koahetsoeng + melamine)e kgothaletswa pele ka lebaka la ho lieha ha yona ho leka-lekaneng ha lelakabe le mocheso o ka lokiswang. Haeba NH₃ e lokela ho qojwa,litsamaiso tsa metsoako ea azokapalitsamaiso tsa ho lokolla CO₂ tse kentsoeng ka har'a capsuleke mekhoa e meng e sebetsang. Netefatso ea liteko e etsoang ka mekhahlelo e eletsoa ho netefatsa botsitso ba electrochemical le ho khoneha ha ts'ebetso.

Let me know if you’d like any refinements! Contact by email: lucy@taifeng-fr.com